Claims for Patent: 5,216,007
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Summary for Patent: 5,216,007
| Title: | Substituted ethylene imidazole and triazoles |
| Abstract: | This invention relates to substituted ethylenic imidazoles and triazoles, their enantiomorphs, acid addition salts and metal complexes as well as their methods of preparation and use as broad spectrum systemic fungicides useful in controlling phytopathogenic fungi such as barley net blotch (Helminthosporium teres), bean powdery mildew (Erysiphe polygoni), peanut cercospora (Cercospora arachidicola), and wheat stem rust (Puccinia graminis f. sp. tritici race 15B-2). |
| Inventor(s): | Miller; George A. (Maple Glen, PA), Chan; Hak-Foon (Walnut Creek, CA) |
| Assignee: | Rohm and Haas Company (Philadelphia, PA) |
| Application Number: | 07/823,041 |
| Patent Claims: |
1. A compound 1-[2-(2,4-dichlorophenyl) hex-1-enyl]-1,2,4-triazole.
2. A fungicidal composition for controlling phytopathogenic fungi which comprises, an agronomically acceptable carrier and an active ingredient, a fungicidally effective amount of 1-[2-(2,4-dichlorophenyl)hex-1-enyl]-1,2,4-triazole. 3. A method for controlling phytopathogenic fungi which consists of applying to a plant, to plant seed or to plant habitat, a fungicidally effective amount of 1-[2-(2,4-dichlorophenyl) hex-1-enyl. 4. A compound of the formula ##STR9## wherein: Z is phenyl or naphthyl or phenyl or naphthyl substituted with up to three substituents selected from the group consisting of halogen, nitro, trihalomethyl, cyano, (C.sub.1 -C.sub.6)alkyl, (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, (C.sub.1 -C.sub.6)alkylsulfinyl and (C.sub.1 -C.sub.6)alkylsulfonyl; R.sup.1 is (C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.8)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.5 -C.sub.8)cycloalkenyl, (C.sub.2 -C.sub.8)alkynyl, phenyl, naphthyl, or phenyl or naphthyl substituted with up to three substituents selected from the group consisting of halogen, nitro, trihalomethyl, cyano, (C.sub.1 -C.sub.6)alkyl, (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, (C.sub.1 -C.sub.6)alkylsulfinyl, and (C.sub.1 -C.sub.6)alkylsulfonyl; R.sup.2 is phenyl or phenyl substituted with from one to three substituents selected from the group consisting of halogen, nitro, trihalomethyl, cyano, (C.sub.1 -C.sub.6)alkyl, (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, (C.sub.1 -C.sub.6)alkylsulfinyl, and (C.sub.1 -C.sub.6)alkylsulfonyl; Q is 1-imidazolyl, or 1- or 4-(1,2,4-triazolyl); and the agronomically acceptable enantiomorphs, geometric isomers, acid addition salts and metal salt complexes containing at least one metal cation selected from the group consisting of magnesium, manganese, copper, nickel, zinc, iron, cobalt, calcium, mercury, chromium, lead and barium thereof. 5. A compound of the formula ##STR10## wherein: Z is phenyl or naphthyl or phenyl or naphthyl substituted with up to three substituents selected from the group consisting of halogen, nitro, trihalomethyl, cyano, (C.sub.1 -C.sub.6)alkyl, (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, (C.sub.1 -C.sub.6)alkylsulfinyl and (C.sub.1 -C.sub.6)alkylsulfonyl; R.sup.1 is hydrogen; R.sup.2 is phenyl substituted with from one to three substituents selected from the group consisting of halogen, nitro, trihalomethyl, cyano, (C.sub.1 -C.sub.6)alkyl, (C.sub.1 -C.sub.6)alkoxy, (C.sub.1 -C.sub.6)alkylthio, (C.sub.1 -C.sub.6)alkylsulfinyl, and (C.sub.1 -C.sub.6)alkylsulfonyl; Q is 1-imidazolyl, or 1- or 4-(1,2,4-triazolyl); and the agronomically acceptable enantiomorphs, geometric isomers, acid addition salts and metal salt complexes thereof. |
